INTERACTIVE EXPLANATIONWhat makes carbon different from oxygen?
Change particle counts, pin the differences, and discover what names an element. Then prepare one-electron hydrogen states, collect possible position outcomes and match energy gaps to light.
Enable JavaScript to change the conditions and run the interactive experiment.
Make a discovery
Protons name the element. Neutrons change the isotope. Electrons change the charge. Where an electron may be found is a different question—and a cloud of possible outcomes is not an orbit.
- Use proton, neutron and electron counts to identify an element, isotope and charge independently.
- Distinguish mass number, measured isotope mass and average atomic weight.
- Explain what one simulated dot means without adding electrons or inventing a trajectory.
- Compare probability per volume, probability across a spherical shell and probability inside a sphere.
- Locate the 2s radial node and the chosen 2p_z nodal plane.
- Use a permitted hydrogen energy gap to predict a vacuum wavelength, then compare an approximation with attributed evidence.
Make a prediction
Six protons, seven neutrons and six electrons. What is it?
- Neutral carbon-13
- Neutral nitrogen-13
- Carbon-13 with charge +1
Read the explanation
Six protons names carbon. Six plus seven nucleons gives mass number 13. Equal proton and electron counts give zero charge.
Understand it
Start with the proton inventory
A nucleus with six protons belongs to carbon. Eight protons identifies oxygen. Carbon occurs in a pencil’s graphite; oxygen is part of water molecules. Those familiar materials contain interacting atoms, not the isolated hydrogen atom used later in this lesson.
Keep the name, change another count
Carbon-12 has six protons and six neutrons. Add one neutron to make carbon-13. Remove one electron instead, and carbon-12 gains charge +1 while its nucleus stays the same. Pin a card and change one column to see exactly what changed.
Change the question—and the model
The probability bench prepares isolated hydrogen-1: one proton and one electron. It does not use the carbon inventory to guess a carbon cloud. Choose a state, then collect simulated position outcomes from many separate identical preparations.
A cloud is not a flight path
Every dot is one possible measurement outcome in a new preparation. The dots accumulate; they do not race around the center or join into a route. More samples reveal a distribution without adding electrons to any one atom.
Move a question through space
The radius probe asks what fraction of outcomes lie inside a sphere. It is an inspection boundary, not an atom’s shell. Compare the exact enclosed probability with the sample fraction. A bigger sample changes the estimate’s variability, not the state’s exact probability.
Connect an energy difference to light
For the selected permitted emission routes, the atom loses energy and a photon carries the same amount. A larger gap gives a shorter wavelength. The ultraviolet example is labeled as invisible ultraviolet, not colored as ordinary visible purple light.
Look closer at the science
Exact counting, limited nuclear reference facts
Atomic number Z is proton count. Mass number A = Z + N counts nucleons; charge number is Z − Ne. Charge Q = (Z − Ne)e, with e = 1.602176634 × 10⁻¹⁹ C exactly. The eight curated ground-state entries are from IAEA LiveChart. Unlisted configurations receive no inferred stability label. Charge arithmetic does not determine which isolated ions can bind all selected electrons.
Mass number is not a measured mass
Carbon-13 has A = 13, while NIST lists its neutral-atom relative mass near 13.00335483507. Carbon’s standard atomic-weight interval is [12.0096, 12.0116]. Those are distinct quantities. Electrons have nonzero mass, but electron count does not enter the integer mass number.
A declared hydrogen approximation
We use a nonrelativistic, spin-independent Coulomb model of hydrogen-1 with reduced electron–proton mass. The relative-coordinate scale a = a₀(1 + me/mp) is about 52.9465 pm. CODATA 2022 constants give RH = R∞/(1 + me/mp), binding scale B = hcRH ≈ 13.5983 eV, and En = −B/n² relative to separated particles at rest.
Density and wavefunction
With x = r/a, the normalized spatial amplitudes are ψ1s = exp(−x)/√(πa³), ψ2s = (2−x)exp(−x/2)/√(32πa³), and ψ2pz = x cosθ exp(−x/2)/√(32πa³). Probability density is |ψ|², in pm⁻³ here. Probability in a region is its volume integral. A continuous density assigns zero probability to an exact point.
A radial shell adds its geometry
Integrating over directions gives radial densities per pm: 4x²exp(−2x)/a for 1s, x²(2−x)²exp(−x)/(8a) for 2s, and x⁴exp(−x)/(24a) for 2p. The 1s spatial density peaks at the origin, while its radial-shell density peaks at r = a. The shell’s growing volume explains the difference; it does not define an orbit.
Sampling a state without a trajectory
The seeded sampler draws the correct radial and angular distributions. For 2p_z, cosθ has density 3cos²θ/2; it is not uniform. Samples come from independent identical preparations. A stationary energy state has a time-independent position density in this model. Presentation time only reveals additional trials.
A node is a zero, not a wall
For 2s, density vanishes on r = 2a, but approximately 5.2653% of probability lies inside that sphere. For the chosen real 2p_z state, density vanishes in the plane z = 0. The analytic slice samples density at a plane; the projected dots are different data.
Spectral scope and evidence
Only 2p → 1s, 3p → 2s and 4p → 2s are offered as electric-dipole emission examples. The 3p/4p cards use energies; no unsupported clouds are drawn for them. A matching energy is not a complete absorption-probability rule. The 2s → 1s route is not an ordinary allowed one-photon electric-dipole transition.
A useful approximation can miss precision evidence
The 2011 Parthey et al. experiment measured a 1S–2S hyperfine-centroid transition frequency of 2,466,061,413,187,035(10) Hz using two-photon spectroscopy. The simple model predicts about 2,466,038,423,686,301 Hz. The discrepancy is much greater than the experimental uncertainty. This is the total transition frequency, not each probe photon’s frequency.
Where this is used
Read an isotope label
The number after an element name counts nucleons. It does not replace the proton number or tell you the electrical charge. Keeping those roles separate helps interpret isotope references.
Understand a calculated image
A density slice, a projection of simulated outcomes and a microscope recording can look similar. Ask what quantity generated the pixels and which physical system it describes.
Use light as a test of a model
Energy differences connect atomic models to spectra. Preserving units, medium, uncertainties and source provenance lets a near match remain a meaningful comparison rather than an exaggerated claim.
Try it yourself: Count an identity. Sample a cloud on paper.
Supplies
- Paper and pencil
- Three counter columns labeled protons, neutrons, electrons
- Ten paper digit cards: 0–9
- A tally row for each of five radius bins
- Make three carbon cards
Write counts 6/6/6, 6/7/6 and 6/6/5 in proton/neutron/electron order. Calculate element, mass number and charge. Circle the one count that changed on each comparison.
- Draw digits with replacement
Mix the ten digit cards. Draw one for the tens place, replace it, mix, then draw one for the ones place and replace it. The ordered pair gives a number from 00 to 99. Each new trial uses the same full set.
- Assign a radius bin
00–31: below a. 32–75: a to below 2a. 76–93: 2a to below 3a. 94–98: 3a to below 4a. 99: 4a or farther. These paper probabilities round the hydrogen 1s model; the final bin preserves an outer tail.
- Collect independent outcomes
Predict the most common bin, then record 30 trials. Put one tally per result. Do not join outcomes into a line or treat the cards as successive electron locations.
- Combine and compare
Optionally combine another 30 trials. Expected paper proportions are 32%, 44%, 18%, 5% and 1%. Exact counts need not match; each finite sample fluctuates. The analytic 1s probabilities differ slightly from these rounded bins.
- Explain what each symbol means
One tally is one simulated outcome from a new identical preparation. Each preparation still has one electron. State two limits: random variation and rounding of the analytic probabilities. Save your prediction, tally and explanation.
Can a paper game reveal a probability pattern without drawing an orbit?
A fictional counting and sampling activity. No radiation source, chemical, flame, laser, ultraviolet lamp, discharge tube or electrical apparatus. Counters are symbols; the game does not measure real atoms.
Check your understanding
Which card is neutral carbon-13?
- 6 protons, 7 neutrons, 6 electrons
- 7 protons, 6 neutrons, 7 electrons
- 6 protons, 7 neutrons, 5 electrons
Answer and explanation
6 protons, 7 neutrons, 6 electrons Protons name carbon, nucleons give 13, equal proton/electron counts give neutrality.
Remove one electron from neutral carbon-12. What changes?
- It becomes carbon-11
- It becomes carbon-12 with charge +1
- It becomes boron-12
Answer and explanation
It becomes carbon-12 with charge +1 The nucleus and mass number stay unchanged. Removing negative charge makes the charge number more positive.
A counter combination is absent from the small nuclear table. What can the lesson still establish?
- It decays immediately
- Equal proton/neutron counts guarantee stability
- Its element, mass number and charge, while nuclear properties remain unspecified
Answer and explanation
Its element, mass number and charge, while nuclear properties remain unspecified Exact bookkeeping and a limited evaluated reference table are separate.
The hydrogen view contains 2,048 dots. What do they represent?
- Independent simulated outcomes from 2,048 identical preparations
- 2,048 electrons in one hydrogen atom
- Consecutive points along an electron’s route
Answer and explanation
Independent simulated outcomes from 2,048 identical preparations Each preparation contains one electron; the plot accumulates outcomes.
Why can 1s radial-shell probability peak away from the point of highest density?
- The electron must orbit there
- A larger-radius shell includes a growing volume factor
- The center has exactly 100% probability
Answer and explanation
A larger-radius shell includes a growing volume factor Density per volume and integrated probability across a spherical shell answer different questions.
The 2s node is the sphere r = 2a. What does it mean?
- A solid wall is inserted there
- There is no probability anywhere inside it
- Density is zero on that surface, with probability on both sides
Answer and explanation
Density is zero on that surface, with probability on both sides About 5.27% lies inside the node. A nodal surface is not a physical wall.
Which selected photon carries more energy: near 656 nm or near 122 nm in vacuum?
- 656 nm because it is longer
- 122 nm because its atomic energy gap is larger
- They are equal because both come from hydrogen
Answer and explanation
122 nm because its atomic energy gap is larger E = hc/λ. The gaps are approximately 1.89 eV and 10.2 eV.
The approximation is close to a measurement but misses by much more than the experimental uncertainty. What follows?
- Replace the measurement with the simpler number
- The same cloud now predicts oxygen exactly
- The model captures a scale while the discrepancy exposes omitted physics
Answer and explanation
The model captures a scale while the discrepancy exposes omitted physics Useful models have testable limits. A hydrogen approximation does not become a multi-electron model.
Sources and model limits
- The counting desk is an inventory representation, not a nucleus geometry, ion-binding calculation or nuclear decay simulation.
- The quantum bench always concerns one isolated hydrogen-1 atom with one electron. It does not derive oxygen, carbon, molecules or materials from a hydrogen cloud.
- The Coulomb model omits spin, relativity, radiative corrections, fine/hyperfine structure, proton finite size, fields and measurement dynamics.
- Every dot represents a separate simulated outcome. Accumulation order is not a particle trajectory, detector film or non-invasive tracking of one electron.
- The 30a radial display limit is declared; probability outside it is not renormalized away. Dot size and the proton-location marker are enlarged for visibility.
- The analytic slice uses a stated logarithmic display mapping shared by states. Screen brightness and dot opacity are not physical emission or charge density.
- The radius probe is a chosen question boundary, not an atom’s hard edge. Changing it leaves the quantum state fixed.
- Vacuum model wavelengths are kept distinct from NIST air entries. Screen colors and line widths do not predict calibrated spectral color, intensity or lifetime.
- The paper activity samples a rounded distribution. It requires no chemical, flame, laser, ultraviolet lamp or electrical apparatus.
Real graphite specimen photograph
U.S. Geological Survey, Communications and Publishing. The image-specific source marks public domain. Source JPEG unchanged, with a central crop in the page; not an atom image.
USGS · Graphite Lump 2Element identity and isotope comparisons
DOE’s isotope explanation, including carbon examples. Nuclear-status badges use the separate evaluated subset.
U.S. DOE · IsotopesElement symbols and atomic-number mapping
Fixed H through O symbol mapping. Missing nuclear facts are not filled by an arithmetic stability rule.
NIST · Atomic-number indexEight curated nuclear ground-state classifications
LiveChart CSV ground_states queries for 1h, 2h, 12c, 13c, 14c, 16o, 17o and 18o. Stable is the reference classification with no observed radioactive decay, not a prediction about selected electron binding.
IAEA · LiveChart data APIElectron mass, elementary charge, length scale and spectral constants
CODATA 2022. Electron mass is nonzero. Exact SI h, c and e are distinct from experimentally adjusted constants.
NIST · CODATA 2022 constantsMass number versus isotope mass and average atomic weight
Carbon isotope masses and standard atomic-weight interval. Only narrow cited factual values are reproduced.
NIST · Carbon isotope massesHydrogen Coulomb wavefunctions, reduced mass and radial probability
Lecture notes pp. 1–7. All lesson plots are authored from equations; MIT figures are not redistributed.
MIT · Hydrogen atom notesWavefunction and position probability are different quantities
Institutional teaching source. A probability cloud is not an electron path.
MIT · Hydrogen wavefunctions and orbitalsStationary-state density and time-dependent amplitude phase
Separation of stationary-state time dependence. The lesson does not animate a trajectory.
MIT · Wavefunctions lectureSelected line configurations, wavelengths and air/vacuum context
The NIST handbook’s calculated selected reference lines are distinguished from a raw measured spectrum and from this browser approximation.
NIST · Persistent hydrogen linesReference energy levels for a common vacuum comparison
The narrow 3p/2s level difference can be converted to wavelength. It is a derived reference value, not new measured data.
NIST · Hydrogen levelsOriginal precision measurement of the 1S–2S transition
Parthey et al., PRL 107, 203001 (2011), two-photon spectroscopy, 5.8 K atomic beam. Attributed result, no paper figure copied.
Parthey et al. · 2011 original manuscriptCarbon in graphite and everyday pencil context
The familiar object establishes context; the app does not model graphite bonding or a material’s full properties.
Royal Society of Chemistry · CarbonOxygen in water and distinction from isolated atoms
An oxygen atom’s inventory is not a water-molecule geometry or an isolated oxygen-ion stability prediction.
Royal Society of Chemistry · OxygenIndependent subject review is pending.
Read the sources and model assumptions